The premixed combustion characteristics of the fuel mixture of carbon monoxide, hydrogen and nitrogen (CO-H2-N2) were studied by numerical simulations with detailed chemistry, and were compared with those of the mixture of hydrogen and nitrogen (H2-N2), and the mixture of methane and nitrogen (CH4-N2). The compositions of the latter two mixtures were set to have the same adiabatic flame temperatures as the CO-H2-N2 flame at the stoichiometric condition. One-dimensional flames, coflow premixed flames and conterflow premixed (twin) flames were adopted as the objects of this study. The dependence of the burning velocity on the equivalence ratio and the pressure, and the flame structures of the one-dimensional flames and the coflow flames were investigated in detail. In addition, the response of the maximum temperature of counterflow flames to the injection velocity was investigated to check the effect of a flame stretch. As a result, it was found that the absolute value of the burning velocity and the flammability limits of CO-H2-N2 flames are similar to those of H2-N2 flames and much different from those of CH4-N2 flames. It was also found that H2 is much more actively consumed than CO at the flame surface of the rich CO-H2-N2 premixed flame, which causes a large unbalance of remaining concentrations between CO and H2 in the region beyond the flame. In the rich coflow CO-H2-N2 flame, conversion from CO to H2 occurs in the region between the inner flame and the outer flame. In the counterflow premixed CO-H2-N2 flame, the thermal-diffusive unbalance occurs similarly to the H2-N2 flame, due to the fast diffusion of H2 toward the flame surface.
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